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Experimental determination of the phase diagrams of the Co-Ni-X (X = W, Mo, Nb, Ta) ternary systems using diffusion multiples

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Abstract Phase stability information regarding the formation of the topologically close packed (TCP) phases is critical for the design of advanced Ni-based and Co-based superalloys that contain high concentrations of… Click to show full abstract

Abstract Phase stability information regarding the formation of the topologically close packed (TCP) phases is critical for the design of advanced Ni-based and Co-based superalloys that contain high concentrations of refractory elements. Isothermal sections of the Co-Ni-W, Co-Ni-Mo, Co-Ni-Nb and Co-Ni-Ta systems at both 900 °C and 800 °C were constructed for the first time from electron probe microanalysis (EPMA) and electron backscatter diffraction (EBSD) measurements on two Co-CoAl-Cr-Mo-Ni-Nb-Ta-W diffusion multiples. The new data will serve as experimental input to future thermodynamic assessments of the Co-Ni-X ternary systems in order to improve the thermodynamic databases for the design and development of advanced Ni-based and Co-based superalloys.

Keywords: ternary systems; experimental determination; determination phase; diffusion multiples

Journal Title: Intermetallics
Year Published: 2018

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