LAUSR

Abstract The solid-liquid equilibria in the system Sn–Zr were investigated experimentally by using the spot technique (thermo-optometry based technique) and differential thermal analysis. The liquidus in the composition range 0–80 at.% Zr was experimentally established. The solidus-liquidus in the composition range 80–100 at.% Zr and all other invariant equilibria have also been re-established. The temperature pertaining to the congruent melting η ↔ Liq at 2279 ± 5 K had been found to be 14 K higher than the value presented in a recent thermodynamic assessment. The temperature corresponding to the peritectic reaction η + Liq ↔ ZrSn2 was found to be 1449 ± 9 K. The temperatures pertaining to the two peritectoid reactions reported in the system η + β-Zr ↔ A15 and β-Zr + A15 ↔ α-Zr were redetermined and were found to be 1473 ± 5 K and 1234 ± 5 K respectively. These values differ from the earlier measurements significantly and are more precise. All these phases were characterized by X-ray diffraction (XRD). The experimental liquidus data obtained were found to be in good agreement with the values obtained by interpolating the phase boundaries suggested in a recent thermodynamic assessment. All the liquidus measurements have been carried out in home made Y2O3 crucibles. The chemical compatibility of a zirconium rich alloy containing 75 at.% Zr with the crucible had also been examined by using Scanning Electron Microscopy along with Energy Dispersive X-ray Analysis. Our study indicates that Y2O3 crucibles are compatible with Sn-75 at.% Zr alloy. The data reported in this study are more precise, reliable and supersede those reported earlier.