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Combinatorial synthesis of high entropy alloys: Introduction of a novel, single phase, body-centered-cubic FeMnCoCrAl solid solution

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Abstract We introduce a novel, FeMnCoCrAl high entropy alloy synthesized by combinatorial sputtering and casting. The synthesized thin film library, exhibiting multiple concentration gradients, is characterized using X-ray diffraction, transmission… Click to show full abstract

Abstract We introduce a novel, FeMnCoCrAl high entropy alloy synthesized by combinatorial sputtering and casting. The synthesized thin film library, exhibiting multiple concentration gradients, is characterized using X-ray diffraction, transmission Kikuchi diffraction and atom probe tomography, to elucidate the impact of Al concentration on phase formation. Experimental results and ab-initio calculations show that single phase, body-centered-cubic solid solutions are formed in an Al concentration range extending the equiatomic composition by ±6 at.%. This underlines the ability of the FeMnCoCrAl high entropy alloy family to form single phase solid solutions at non-equiatomic compositions and hence with varying configurational entropy contributions.

Keywords: phase; phase body; high entropy; single phase; body centered

Journal Title: Journal of Alloys and Compounds
Year Published: 2017

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