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Progress on phase equilibria of the AlSiZr system at 700 and 900 °C

Abstract Phase equilibria of the Al Si Zr system were investigated using equilibrated alloys. All alloys were studied by X-ray powder diffraction, scanning electron microscopy and energy dispersive spectroscopy. The… Click to show full abstract

Abstract Phase equilibria of the Al Si Zr system were investigated using equilibrated alloys. All alloys were studied by X-ray powder diffraction, scanning electron microscopy and energy dispersive spectroscopy. The ternary phase τ 1 was found at 700 and 900 °C, while the τ 2 phase was only identified at 900 °C. 12 three-phase regions were experimentally determined in isothermal sections of the Al Si Zr system at both 700 and 900 °C. The solubility of Si in the intermediate and solution phases (i.e. Al 3 Zr, Al 2 Zr, Al 3 Zr 2 , AlZr 3 , α-Al and (Zr)) at the Al Zr side is limited, whereas the solubility of Al in the Si Zr intermetallic (except the Si 2 Zr 3 phase) is reverse. In addition, Al in the αSiZr phase at 900 °C decreased to 0.5 at.% from 10.3 at.% at 700 °C.

Keywords: phase; phase equilibria; system 700; 700 900

Journal Title: Journal of Alloys and Compounds
Year Published: 2017

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