Abstract Non-stoichiometric YFe 1.5 Al 0.5-x , YFe 1.6 Al 0.4-x and YFe 1.7+x Al 0.3 ( x = 0.1 and 0.2) compounds with single C15 Laves phase were successfully prepared.… Click to show full abstract
Abstract Non-stoichiometric YFe 1.5 Al 0.5-x , YFe 1.6 Al 0.4-x and YFe 1.7+x Al 0.3 ( x = 0.1 and 0.2) compounds with single C15 Laves phase were successfully prepared. Compared with stoichiometric compounds, enhanced hydrogenation capacity and hydrogen absorption rate were obtained in hypo-stoichiometric compounds, and increased dehydrogenation equilibrium pressure was achieved for hyper-stoichiometric compounds. The YFe 1.6 Al 0.2 compound shows the maximum reversible absorption capacity of 3.04 H/f.u. (1.63 wt.%), which is 18% higher than that of YFe 1.5 Al 0.5 . Faster hydrogenation kinetics could be obtained in all of the hypo-stoichiometric samples, completing hydrogenation within 300 s at 100 °C. The YFe 1.7+x Al 0.3 compounds showed elevated desorption equilibrium pressure, indicating higher dehydrogenation capacity than that of stoichiometric compounds. The present work demonstrates the positive effect of non-stoichiometry on the Y-Fe-Al ternary compounds and plays a guiding role for improving the hydrogen storage properties of AB 2 -type rare earth-transition metal alloys.
               
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