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Growth of hierarchical birnessite-type Cu0.45Mn0.55O2 nanosheets on flexible carbon textile for high-performance supercapacitors electrode

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Abstract The fabrication of high capacitance binder-free electrode materials with the advantages of having low costs and low toxicity has been attracting great attention for supercapacitors. In this study, we… Click to show full abstract

Abstract The fabrication of high capacitance binder-free electrode materials with the advantages of having low costs and low toxicity has been attracting great attention for supercapacitors. In this study, we report the synthesis of hierarchical birnessite-type 3D Cu 0.45 Mn 0.55 O 2 (CMO) nanosheets (NS) directly grown on flexible carbon textile (CT) without any surfactant via a simple hydrothermal method. The CMO-NS supported on carbon textile were directly used as an integrated electrode for electrochemical measurments. The binder-free electrodes yielded high specific capacitance of 983 F g −1 in 1.0 M Na 2 SO 4 aqueous electrolyte at a constant current density of 1.0 mAcm −2 . In addition, the CMO-NS electrode displayed outstanding cyclic stability by retaining 90% capacitance after 3000 cycles. Thus, the Cu 0.45 Mn 0.55 O 2 nanosheets combined with carbon textile form a promising electrode material for high-performance pseudocapacitors that have light weight and low cost.

Keywords: birnessite type; carbon; carbon textile; hierarchical birnessite; flexible carbon

Journal Title: Journal of Alloys and Compounds
Year Published: 2017

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