Abstract Carbon/Carbon (C/C) composites modified with ZrC and SiC particles were prepared by precursor infiltration and pyrolysis (PIP) process. Effects of the simulated low earth orbit environment including the vacuum… Click to show full abstract
Abstract Carbon/Carbon (C/C) composites modified with ZrC and SiC particles were prepared by precursor infiltration and pyrolysis (PIP) process. Effects of the simulated low earth orbit environment including the vacuum environment (under the high-vacuum state of 1.3 × 10 −3 Pa) and low-temperature thermal cycling (the temperature is ranged from 153 K to 393 K for 200 times) on C/C-ZrC-SiC composites were investigated. These results show that the significantly generated microcracks, interspaces and interface debondings contributed to the increase of open porosity. The interfacial damages of C/C-ZrC-SiC composites caused by low-temperature thermal cycling in short-cut webs and non-woven webs were generated at fiber/matrix interface and fiber bundle/matrix interface, respectively. The flexural strength of C/C-ZrC-SiC composites increased by 9.35% after 100-time thermal cycles and then decreased dramatically to 83.99% of pristine strength after 200-time thermal cycles, accompanied by the transformation of fracture behavior from the brittle fracture mode into the pseudo-plastic fracture mode. In addition, the defects induced by the low-temperature thermal cycling accelerated the oxidative damage of C/C-ZrC-SiC composites during thermal shock between 1773 K and room temperature.
               
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