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An excellent strategy for synthesis of coral-like ZnFe2O4 particles for capacitive pseudocapacitors

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Abstract Herein, coral-like ZnFe 2 O 4 particles were prepared by a stepwise strategy, which contains a synthesis process and a subsequent etching process. Etching process can greatly improve the… Click to show full abstract

Abstract Herein, coral-like ZnFe 2 O 4 particles were prepared by a stepwise strategy, which contains a synthesis process and a subsequent etching process. Etching process can greatly improve the specific surface area of the ZnFe 2 O 4 . The specific surface area of the coral-like ZnFe 2 O 4 particles is 200 times larger than that of the un-etched ZnFe 2 O 4 particles. The ferric ion of ZnFe 2 O 4 can be reduced gradually by hydrazine to form Fe 2+ , which will be coordinated with methyl mercaptoacetate to dissolve in DMF. Etched coral-like ZnFe 2 O 4 particles have been tested as an electrode material for supercapacitor through electrochemical analysis. Etched coral-like ZnFe 2 O 4 particles display a larger specific capacitance (∼471 F g −1 ) than the un-etched ZnFe 2 O 4 particles (∼162 F g −1 ) at a scan rate of 2 mV s −1 . An excellent stability of cycling performance with 80.6% specific capacitance retention after 3000 cycles can be achieved. The results suggest that the as-prepared coral-like ZnFe 2 O 4 particles might be of potential application for supercapacitor electrode materials. The strategy paves an efficient way for synthesizing new ferrite particles with high specific surface area for the electrode material of supercapacitor.

Keywords: coral like; znfe particles; znfe; like znfe; strategy; synthesis

Journal Title: Journal of Alloys and Compounds
Year Published: 2017

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