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Enhanced luminescent properties in Eu3+-activated SrMoxW1-xO4 red-emitting phosphors for solid-state lighting and field-emission displays

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Abstract We fabricated the trivalent Eu 3+ -activated SrMo x W 1- x O 4 phosphors by a high-temperature solid-state reaction technique. The prepared phosphors were characterized by X-ray diffraction… Click to show full abstract

Abstract We fabricated the trivalent Eu 3+ -activated SrMo x W 1- x O 4 phosphors by a high-temperature solid-state reaction technique. The prepared phosphors were characterized by X-ray diffraction patterns, field-emission scanning electron microscope images, luminescence decay curves, photoluminescence (PL) spectra, and cathodoluminescence (CL) spectra. Under the ultraviolet (UV) illumination, the emissions of Eu 3+ ions with an intense peak at 615 nm were observed, indicating the Eu 3+ ions occupied at the low symmetry sites without inversion in host lattices. With the addition of the Mo 6+ ions, the emission intensity of the studied samples was increased and the optimum result was obtained when x  = 0.9. The temperature-dependent PL emission spectra were measured to explore the thermal stability of the resultant compounds. The final products emitted visible red emissions with high color purity of 95.1%. The CL spectra revealed that the synthesized compounds also exhibited superior CL performance. These characteristics make the Eu 3+ -activated SrMo x W 1- x O 4 red-emitting phosphors a promising candidate for UV-based white light-emitting diode and field-emission display applications.

Keywords: solid state; emitting phosphors; field emission; red emitting; emission

Journal Title: Journal of Alloys and Compounds
Year Published: 2017

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