Abstract Hydrogen is regarded as a highly efficient and clean renewable energy source. However, the high cost of preferred platinum catalysts becomes an economic burden for its commercial applications. Therefore,… Click to show full abstract
Abstract Hydrogen is regarded as a highly efficient and clean renewable energy source. However, the high cost of preferred platinum catalysts becomes an economic burden for its commercial applications. Therefore, the development of cost-effective and robust catalysts, having superior catalytic activity toward hydrogen evolution reaction (HER), is a prerequisite to realize large-scale hydrogen production. We present here a simple electrodeposition strategy of building nickel based alloy catalysts (NiM, M = Co, Cu, Mo, Au, Pt) on titanium (Ti) foils, which are subsequently utilized for catalyzing HER by seawater splitting. The preliminary results demonstrate that the Ti/NiCo and Ti/NiCo electrodes have superior catalytic activity for HER in seawater. All the Ti/NiM electrodes show relatively good long-term stability at −1.0 V vs. RHE over 10 h. The high efficiency and reasonable stability of the alloy catalysts demonstrate promising applications in the rising hydrogen revolution.
               
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