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Preparation of anatase/rutile TiO2/SnO2 hollow heterostructures for gas sensor

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Abstract TiO2 hollow hierarchical architectures with anatase and rutile phases are fabricated. The hierarchical structure uniformly decorated with SnO2 nanoparticles endows a fascinating sensing performance for detecting triethylamine (TEA). Hierarchical… Click to show full abstract

Abstract TiO2 hollow hierarchical architectures with anatase and rutile phases are fabricated. The hierarchical structure uniformly decorated with SnO2 nanoparticles endows a fascinating sensing performance for detecting triethylamine (TEA). Hierarchical structure provides a close connection between anatase/rutile TiO2 and SnO2, which is in favor of efficient electrons transfer. It is found that TiO2@SnO2 as a novel sensing material has high response at low level of TEA and rapid responding speed in comparison with individual TiO2 components. In the case of 5 ppm TEA gas under the operation temperature of 240 °C, the response value of TiO2@SnO2 sample is up to 21.6, which is three times higher than that of TiO2 sample. The responding speed of TiO2@SnO2 sensors elevates 28% in comparison with TiO2. This result is utilizable for developing the high efficiency gas sensors using hollow hierarchical architecture.

Keywords: tio2; tio2 sno2; gas; rutile tio2; anatase rutile

Journal Title: Journal of Alloys and Compounds
Year Published: 2018

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