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Comparison of optical properties of Cr-doped Bi12TiO20 and Fe-doped Bi12SiO20

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Abstract Optical investigations of Cr-doped Bi12TiO20 were performed at T = 300 , 77 and 4.2 K. An absorption line at λ = 456 nm at T = 4.2 K was… Click to show full abstract

Abstract Optical investigations of Cr-doped Bi12TiO20 were performed at T = 300 , 77 and 4.2 K. An absorption line at λ = 456 nm at T = 4.2 K was detected. Line corresponds to E 5 → T 2 5 transition of Cr2+ ion located at tetrahedral position of the sillenite cell. This conclusion was confirmed by observation of the Zeeman effect in magnetic field up to 14 T. These results for Cr-doped Bi12TiO20 are similar to those for Fe-doped Bi12SiO20. Details of the absorption line structure of Fe-doped Bi12SiO20 are explained by the Jahn-Teller effect.

Keywords: doped bi12sio20; comparison optical; doped bi12tio20; properties doped; optical properties

Journal Title: Journal of Alloys and Compounds
Year Published: 2019

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