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Preparation of radial ZnSe-CdS nano-heterojunctions through atomic layer deposition method and their optoelectronic applications

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Abstract Radial 1-D nano-heterojunctions have distinct optoelectronic properties. However, their complex fabrication process is still the bottleneck of device applications. Herein, a facile atomic layer deposition (ALD) method was used… Click to show full abstract

Abstract Radial 1-D nano-heterojunctions have distinct optoelectronic properties. However, their complex fabrication process is still the bottleneck of device applications. Herein, a facile atomic layer deposition (ALD) method was used to coat a polycrystalline CdS thin film with high uniformity and controllable thickness on the surface of the as-synthesized p-type ZnSe nanowires, for fabricating radial 1-D ZnSe-CdS nano-heterojunctions. The nano-heterojunctions exhibited excellent optoelectronic properties. Under blue/violet light, the nano-heterojunctions obtained a response radio of ∼5 × 103, a responsitivity of ∼1.43 A/W, a gain of ∼3.78 and a detectivity of ∼0.57 × 1012 cmHz1/2W−1 at zero bias. Furthermore, the nano-heterojunction also showed obvious photovoltaic characteristic with a power conversion efficiency of ∼0.96%. This method is expected to play an important role in nano-heterojunction construction and their device applications.

Keywords: nano heterojunctions; method; radial znse; atomic layer; layer deposition

Journal Title: Journal of Alloys and Compounds
Year Published: 2019

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