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Influence of the nitrogen content on the structure and properties of MoNbTaVW high entropy alloy thin films

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Abstract The influence of nitrogen incorporation on the chemical composition, structure, mechanical, and electrical properties of refractory (MoNbTaVW)1−xNx high entropy alloy thin films is investigated. The films were synthesized by… Click to show full abstract

Abstract The influence of nitrogen incorporation on the chemical composition, structure, mechanical, and electrical properties of refractory (MoNbTaVW)1−xNx high entropy alloy thin films is investigated. The films were synthesized by two different physical vapor deposition methods, cathodic arc deposition and direct current magnetron sputtering, onto silicon and polyimide substrates. Regardless of the deposition method, a change from body centered cubic to face centered cubic structure was observed with increasing nitrogen content in the film. This structural change was accompanied by an increase in hardness as measured by nanoindentation but also by a material embrittlement as determined from tensile straining tests.

Keywords: alloy thin; thin films; entropy alloy; influence nitrogen; high entropy; structure

Journal Title: Journal of Alloys and Compounds
Year Published: 2021

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