Abstract Sc3+ (0,0.1,0.3,0.5,0.7 mol%) modified ZnGa2O4 (abbreviated Sc-ZGO) ceramics were synthesized by solid-state method. The relationship between microwave dielectric performance and bonds vibration has been systematically investigated. With Sc3+ modification, the… Click to show full abstract
Abstract Sc3+ (0,0.1,0.3,0.5,0.7 mol%) modified ZnGa2O4 (abbreviated Sc-ZGO) ceramics were synthesized by solid-state method. The relationship between microwave dielectric performance and bonds vibration has been systematically investigated. With Sc3+ modification, the er of Sc-ZGO keeps steady (~10). While τf values (increasing from −71 ppm/°C to −39 ppm/°C) show linear correlation with Sc3+ concentration. And Q×f values climb up to a maximum value and then ramp down. The Q×f value of Sc-ZGO increased by almost 45% compared with normal spinel ZnGa2O4 ceramics. The enhancement of τf and Q×f on Sc modified ZnGa2O4 can be attributed to higher densification, however, further analysis elucidated that short-range cation ordering degree is another governing factor. The influence of Sc3+ modification on ZnGa2O4 bonds vibration has been discussed in detail. 5Sc-ZGO sintered at 1350 °C for 2 h exhibits the best microwave dielectric properties: er = 9.9, Q×f = 124,147 GHz, tanδ = 7.98 × 10−5, and τf = −56 ppm/°C (@9.9 GHz).
               
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