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RGO-Wrapped Ti3C2/TiO2 Nanowires as a Highly Efficient Photocatalyst for Simultaneous Reduction of Cr(VI) and Degradation of RhB Under Visible Light Irradiation

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Abstract A novel photocatalyst of rGO-wrapped Ti3C2/TiO2 nanowires ((Ti3C2/TiO2)@rGO) was successfully synthesized to remove hexavalent chromium (Cr(VI)) and Rhodamine B (RhB) from wastewater. Among the prepared photocatalysts, (Ti3C2/TiO2)@rGO-15 showed the… Click to show full abstract

Abstract A novel photocatalyst of rGO-wrapped Ti3C2/TiO2 nanowires ((Ti3C2/TiO2)@rGO) was successfully synthesized to remove hexavalent chromium (Cr(VI)) and Rhodamine B (RhB) from wastewater. Among the prepared photocatalysts, (Ti3C2/TiO2)@rGO-15 showed the highest photocatalytic activity in both single and mixed pollutant solutions. The excellent photocatalytic activity was ascribed to the enhanced separation efficiency of e- and h+ resulted from the Schottky barrier established in (Ti3C2/TiO2)@rGO. Ti3C2 gathered the stimulated electrons originated from TiO2 and further transferred them to rGO, thus enhancing the separation efficiency of e- and h+. Furthermore, different scavengers were employed to determine the reactive species involved in the photocatalytic reaction system. This work may provide a promising way to promote the separation efficiency of e- and h+ via appropriate incorporation of co-catalyst.

Keywords: ti3c2 tio2; tio2 nanowires; wrapped ti3c2; rgo; rgo wrapped

Journal Title: Journal of Alloys and Compounds
Year Published: 2021

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