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Experimental investigation of phase equilibria in the Ni-Ta-Si refractory alloy system

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Abstract Three isothermal sections of the Ni-Ta-Si ternary system at 1300, 1100 and 900 °C were constructed in the whole composition range and analysed using electron probe microanalysis (EPMA), scanning electron… Click to show full abstract

Abstract Three isothermal sections of the Ni-Ta-Si ternary system at 1300, 1100 and 900 °C were constructed in the whole composition range and analysed using electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. In addition to the known ternary G, E, H and C14 phases, a new compound with the composition of Ni23–25Ta39–40Si35–38 was detected for the first time, herein designated as the F phase. Furthermore, the continuous (Ni, Si)Ta2 phase was found to be stable and the composition range of the ternary C14 Laves phase was revised to be Ni39–54Ta26–33Si13–27. The newly determined phase equilibria in the Ni-Ta-Si ternary system can be useful in guiding alloying strategies or composition design of Ni-based superalloys.

Keywords: system; experimental investigation; investigation phase; composition; phase equilibria; phase

Journal Title: Journal of Alloys and Compounds
Year Published: 2021

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