Abstract With the strategy of in-situ generation of benzyl formates followed by alkoxycarbonylation, a palladium catalyzed carbonylative transformation of benzyl chlorides for the synthesis of benzyl arylacetates and arylacetic acids… Click to show full abstract
Abstract With the strategy of in-situ generation of benzyl formates followed by alkoxycarbonylation, a palladium catalyzed carbonylative transformation of benzyl chlorides for the synthesis of benzyl arylacetates and arylacetic acids have been developed. By employing different acidic and basic additives, both substituted phenylacetic acids and benzyl phenylacetates can be obtained divergently.
Keywords:
benzyl arylacetates;
benzyl;
benzyl chlorides;
arylacetates arylacetic;
palladium catalyzed;
synthesis benzyl
Journal Title: Journal of Catalysis
Year Published: 2018
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Journal Title: Journal of Catalysis
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!