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Abstract Two MgCl2-supported Ziegler-Natta model catalysts were prepared by contacting activated MgCl2 with deficient or excess amount of TiCl4. Ethylene/1-hexene copolymerization with the catalysts was conducted under different 1-hexene feed,… Click to show full abstract
Abstract Two MgCl2-supported Ziegler-Natta model catalysts were prepared by contacting activated MgCl2 with deficient or excess amount of TiCl4. Ethylene/1-hexene copolymerization with the catalysts was conducted under different 1-hexene feed, and active center concentration of the reaction system was determined by quench-labeling method using thiophene-2-carbonyl chloride as the quencher. The catalytic activity was only moderately enhanced (increment
Keywords:
hexene;
ziegler natta;
hexene copolymerization;
ethylene hexene;
mgcl2
Journal Title: Journal of Catalysis
Year Published: 2019
Link to full text (if available)
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Journal Title: Journal of Catalysis
Year Published: 2019
Link to full text (if available)
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recommendations!