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Titanium carbide MXenes coupled with cadmium sulfide nanosheets as two-dimensional/two-dimensional heterostructures for photocatalytic hydrogen production.

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Two-dimensional (2D)/2D heterostructures with close contact are believed to be important for photocatalysis owing to a 2D ultrathin structure, a large surface area, and an efficient carrier separation or transfer.… Click to show full abstract

Two-dimensional (2D)/2D heterostructures with close contact are believed to be important for photocatalysis owing to a 2D ultrathin structure, a large surface area, and an efficient carrier separation or transfer. In this study, we designed and prepared a unique 2D/2D cadmium sulfide (CdS) nanosheet (NS)@titanium carbide (Ti3C2) MXene composite photocatalyst. The results show that the CdS NSs can be controllably assembled on conductive Ti3C2 MXene via a one-step hydrothermal strategy. The 2D/2D CdS NS@Ti3C2 MXene composites with 5 mg of Ti3C2 MXene show a higher photocatalytic performance (1.73 mmol h-1 g-1) than pure CdS NSs (0.37 mmol h-1 g-1) and CdS NS@Ti3C2 MXene composites with other MXene contents (3 mg, 7 mg, 10 mg, and 20 mg). The improved photocatalytic activity can be attributed to the high surface area as confirmed by a BET analysis and enhanced charge separation activity between CdS and Ti3C2 MXene.

Keywords: titanium carbide; dimensional heterostructures; ti3c2 mxene; cadmium sulfide; two dimensional

Journal Title: Journal of colloid and interface science
Year Published: 2022

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