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Bio-lubricants production from fish oil residue by transesterification with trimethylolpropane

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Abstract The fatty acid ethyl esters mixture, a fish oil residue obtained after the extraction of omega-3 polyunsaturated fatty esters, has been converted into mixtures of mono-, di-, and triesters… Click to show full abstract

Abstract The fatty acid ethyl esters mixture, a fish oil residue obtained after the extraction of omega-3 polyunsaturated fatty esters, has been converted into mixtures of mono-, di-, and triesters of trimethylolpropane by transesterification at 100-140 °C under vacuum with sodium ethoxide as catalyst. This method has shown to be more efficient than the enzymatic transesterification using commercially available lipases. The crude reaction mixture (84% conversion of ethyl esters), enriched in trimethylolpropane triesters (96% selectivity) was characterized and its properties compared with those of the starting ethyl esters mixture and the trimethylolpropane esters obtained from vegetal sources.

Keywords: oil residue; production; transesterification; fish oil; trimethylolpropane

Journal Title: Journal of Cleaner Production
Year Published: 2018

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