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A sustainable reduction roasting technology to upgrade the ferruginous manganese ores

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Abstract Reduction roasting of manganese ores is a known process; however, it is not yet commercialized mainly due to various techno-economic issues. The current research work presents results of a… Click to show full abstract

Abstract Reduction roasting of manganese ores is a known process; however, it is not yet commercialized mainly due to various techno-economic issues. The current research work presents results of a large-scale plant trial performed at a commercial Direct Reduced Iron making plant to upgrade low-grade ferruginous manganese ores (Mn: 25-32%, Mn/Fe: ∼1). Trials were carried out using a lot of 2000 of tons low grades ferruginous manganese ores of three different types. Experiments were designed to test 3 levels of two different variables for each type of ore. Raw material feed rate (3, 4.5, and 6tph) and feed coal proportion(25, 29,33 % of ore) were the prime process variables. Process settings were identified and fixed to limit the occurrence of undesired chemical reactions to restrict the formation of complex MnxFe3-xO4 phases and dilution of reducing atmosphere. Ores were crushed into 0-15 mm size, reduce-roasted at 950°C in a rotary kiln, crushed into 15 units (Mn: 30%→46%) and can bring down the Fe content by >15 units (Fe: 27%→12%) in the produced ore concentrate. The developed process could achieve product yield ∼50 % and Mn Recovery>70%. The Mn-rich concentrate was successfully converted into extrusion briquettes and consumed in a submerged arc furnace for ferroalloy making. The iron-rich by-product was successfully used as a sinter mix for steelmaking process. Techno-economic evaluation and sensitivity analysis have also been carried out. Studies indicated that roasting of ferruginous manganese ores at a commercial Direct Reduced Iron plant is an adaptable and sustainable solution to upgrade the low-grade Mn resources in the dynamic global Mn ore market.

Keywords: sustainable reduction; ferruginous manganese; manganese ores; process; reduction roasting

Journal Title: Journal of Cleaner Production
Year Published: 2020

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