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Enhanced efficiency of luminescence with stoichiometry control in LiGd(W (1−x) Mo x O 4 ) 2 :Eu 3+ red phosphors

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Abstract A series of LiGd(W (1−x) Mo x O 4 ) 2 [hereafter LGWM]:Eu 3+ (x=0.00 to 1.00) red-emitting phosphors were synthesized by sol-gel method. Metal nitrates were used as… Click to show full abstract

Abstract A series of LiGd(W (1−x) Mo x O 4 ) 2 [hereafter LGWM]:Eu 3+ (x=0.00 to 1.00) red-emitting phosphors were synthesized by sol-gel method. Metal nitrates were used as starting materials with citric acid as chelator and ethylene glycol as binder. Synthesized gel was pre-fired at 523 K and calcined at 1073 K using resistive furnace in air atmosphere. The crystallinity, surface morphology and luminescent properties of the phosphors were investigated using powder X-ray diffraction (XRD), scanning electron microscope (SEM) and fluorescence spectrophotometry respectively. The intensity of the red emission at 615 nm for 5 D 0 → 7 F 2 electric dipole transition increases as the content of Mo 6+ was increased and reach a maximum, when the relative ratio of W/Mo is 1:1 under 396 nm excitation.

Keywords: efficiency luminescence; stoichiometry control; ligd; luminescence stoichiometry; control ligd; enhanced efficiency

Journal Title: Journal of Crystal Growth
Year Published: 2017

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