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Thermal history effect on the nucleation of oxygen precipitates in germanium doped Cz-silicon studied by high-energy X-ray diffraction

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Abstract The oxygen (O) precipitate growth kinetics from moderate and high germanium (Ge) doped Czochralski-growth silicon (Cz-Si) are in-situ investigated at 1000 ° C utilizing high-energy X-ray diffraction and analyzed… Click to show full abstract

Abstract The oxygen (O) precipitate growth kinetics from moderate and high germanium (Ge) doped Czochralski-growth silicon (Cz-Si) are in-situ investigated at 1000 ° C utilizing high-energy X-ray diffraction and analyzed with respect to precipitate density within a diffusion-driven growth model. Distinct different precipitation kinetics are observed for high Ge doped specimens. From the comparison of three thermal treatments, it was found that even for a high Ge concentration the nucleation rate at 800 ° C is not influenced, however it facilitates larger grown-in precipitates of smaller amount as compared to the precipitates in undoped and moderately Ge doped samples. However, those grown-in O precipitates can be erased either by a direct annealing at 1200 ° C or 1000 ° C , but on the other hand stabilized by an annealing step at 800 °C, which in this manner as a drift step of grown-in precipitates for the high Ge-doped samples. In comparison additional nuclei are formed at 800 °C in the moderate and undoped cases.

Keywords: oxygen; ray diffraction; high energy; germanium doped; energy ray; growth

Journal Title: Journal of Crystal Growth
Year Published: 2017

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