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Defect formation in Si-crystals grown on large diameter bulk seeds by a modified FZ-method

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Abstract The crucible free growth of dislocation free respectively low defect single crystals on large diameter silicon seeds without using the common Dash technique was investigated. A promising concept to… Click to show full abstract

Abstract The crucible free growth of dislocation free respectively low defect single crystals on large diameter silicon seeds without using the common Dash technique was investigated. A promising concept to reach this aim was to reduce the thermal gradients and stresses. Therefore, a combination of RF- and MF heating, additionally to the standard FZ setup, was used by implementation of a further coil which is surrounding the 4 inch diameter seeds. The heat dissipation conditions, the growth velocity and the ratio between RF- and MF power were varied. Crystals were grown with a total length up to 120 mm. After 90 mm of single crystalline growth the crystals became polycrystalline. All grown crystals, independent of the seed structure or preparation procedure, developed a dislocation network during heating already before melting the seed surface and growth start. By noticeable reduction of the thermal stresses the single crystalline status could be maintained for a certain distance and an immediate transition to the polycrystalline growth could be avoided.

Keywords: seed; large diameter; crystals grown; defect formation; growth

Journal Title: Journal of Crystal Growth
Year Published: 2018

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