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Herbicide diuron removal from aqueous solution by bottom ash: Kinetics, isotherm, and thermodynamic adsorption studies

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Abstract The current research reports an efficient methodology of valorizing bottom ash waste generated from the combustion of coal in a local thermal power plant. Where in this work we… Click to show full abstract

Abstract The current research reports an efficient methodology of valorizing bottom ash waste generated from the combustion of coal in a local thermal power plant. Where in this work we have used bottom ash waste (BAW-200) as an inexpensive adsorbent for herbicide diuron removal. The BAW-200 was characterized by XRD, FTIR, SEM and mapping analyses. The adsorption kinetics, equilibrium isotherms and regeneration potential of diuron removal by BAW-200 was investigated in batch tests. Pseudo-first order model described well the kinetic data and Langmuir model show a high correlation with equilibrium data, which suggested monolayer adsorption of diuron onto BAW-200 with a higher adsorption capacity (349.52 mg/g) compared to other adsorbents. The thermodynamic behavior revealed that adsorption phenomenon of diuron onto BAW-200 ensued spontaneously and endothermic in nature. The regeneration method show that BAW-200 can be recycled easily from wastewater using ethanol as solvent. The outcomes show that BAW-200 adsorbent could be used in improving the quality of wastewater as providing a waste disposal option for the industry.

Keywords: adsorption; diuron; bottom ash; diuron removal; baw 200

Journal Title: Journal of environmental chemical engineering
Year Published: 2020

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