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Glucose-derived carbon sphere supported CoP as efficient and stable electrocatalysts for hydrogen evolution reaction

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Abstract Glucose-derived carbon sphere supported cobalt phosphide nanoparticles (CoP/C) were synthesized via a concise two-step method. The electrochemical measurement results indicate that the CoP/C prepared at 900 °C presents excellent electrocatalytic… Click to show full abstract

Abstract Glucose-derived carbon sphere supported cobalt phosphide nanoparticles (CoP/C) were synthesized via a concise two-step method. The electrochemical measurement results indicate that the CoP/C prepared at 900 °C presents excellent electrocatalytic performance for hydrogen evolution reaction (HER). The overpotential at a current density of 10 mA cm −2 is 108 and 163 mV in 0.5 M H 2 SO 4 and 1 M KOH, respectively, and maintains its electrocatalytic durability for at least 10 h. This work supplies a new field to challenge the construction of electrocatalysts for HER through using cost-effective carbon supported transition metal phosphides.

Keywords: carbon; derived carbon; glucose derived; hydrogen evolution; carbon sphere; sphere supported

Journal Title: Journal of Energy Chemistry
Year Published: 2017

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