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Abstract A lipophilic and electron-rich metallophthalocyanine Mn(III)Cl(α,α′-n-OC 5 H 11 ) 8 Pc has been synthesized and characterized. A series of electrochemical experiments demonstrate that the Mn(III)Cl(α,α′-n-OC 5 H 11… Click to show full abstract
Abstract A lipophilic and electron-rich metallophthalocyanine Mn(III)Cl(α,α′-n-OC 5 H 11 ) 8 Pc has been synthesized and characterized. A series of electrochemical experiments demonstrate that the Mn(III)Cl(α,α′-n-OC 5 H 11 ) 8 Pc complex can be used as a catalyst for highly efficient carbon-chloride bond cleavage of environmental toxic hexachlorocyclohexanes (HCHs) through electrochemical catalysis, and that the increased catalytic efficiency is related to the enantiomeric carbon-chloride σ-bond of HCHs.
Journal Title: Journal of Electroanalytical Chemistry
Year Published: 2017
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