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Simulations of single-phase flow in an up-flow electrochemical reactor with parallel plate electrodes in a serpentine array

Abstract This paper deals with hydrodynamics simulations in an up-flow pre-pilot electrochemical reactor with a stack containing eight cells in a serpentine array. Each cell contains horizontal parallel aluminum plate… Click to show full abstract

Abstract This paper deals with hydrodynamics simulations in an up-flow pre-pilot electrochemical reactor with a stack containing eight cells in a serpentine array. Each cell contains horizontal parallel aluminum plate electrodes, open to the atmosphere at the top of the cell. The single-phase flow was simulated solving the Reynolds-Averaged Navier-Stokes (RANS) equations with k - e turbulence model via finite element method. The residence time distribution (RTD) simulations were obtained solving the averaged diffusion-convection equation. The influence of mean linear flow velocity, 2.4 ≤  U  ≤ 12.1 cm s −1 , on the velocity profiles evidenced the presence of jet flow in the first channel of the stack, which is located close to the electrolyte inlet at the bottom of the reactor. Then, the flow pattern became homogeneous in the second and third channels, while the quasi-plug flow profile was developed from the fourth channel to the exit. Streamlines graphs showed that in channel 1 there was very little recirculation of the fluid elements; however, this phenomenon disappears in the subsequent channels. The RTD curves shows the absence of low velocity zones in the reactor, because the electrolyte outlet is open to the atmosphere. The experimental RTD curves showed excellent agreement with simulations.

Keywords: electrochemical reactor; serpentine array; plate electrodes; single phase; flow; reactor

Journal Title: Journal of Electroanalytical Chemistry
Year Published: 2019

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