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Incorporating SnO2 nanodots into wood flour-derived hierarchically porous carbon as low-cost anodes for superior lithium storage

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Abstract Biomass-derived carbon has been intensively investigated as conductive matrix for conversion and alloying-type anodes in batteries. In this work, SnO2 nanodots incorporated in wood flour-derived porous carbon (WFPC) are… Click to show full abstract

Abstract Biomass-derived carbon has been intensively investigated as conductive matrix for conversion and alloying-type anodes in batteries. In this work, SnO2 nanodots incorporated in wood flour-derived porous carbon (WFPC) are synthesized through a hydrothermal method combined carbonization treatment. As anodes in lithium-ion batteries, the fabricated SnO2/WFPC composites deliver a high initial reversible capacity of 1014.4 mAh g−1 at 156 mA g−1 and exhibit superior rate performance (370 mAh g−1 at 783 mA g−1) with capacity retention of 82% after 250 cycles. The improved electrochemical performance can be ascribed to the nanoconfined SnO2 particles embedded in porous conductive carbon with shortened Li+ diffusion length, easy access of electrolyte, and high mechanical integrity, suggesting an efficient way to design high performance electrode materials for batteries.

Keywords: carbon; incorporating sno2; sno2 nanodots; flour derived; wood flour; porous carbon

Journal Title: Journal of Electroanalytical Chemistry
Year Published: 2020

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