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Tb3+/Yb3+ co-doped Y2O3 upconversion transparent ceramics: Fabrication and characterization for IR excited green emission

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Abstract Tb 3+ /Yb 3+ co-doped Y 2 O 3 transparent ceramics were fabricated by vacuum sintering of the pellets (prepared from nanopowders by uniaxial pressing) at 1750 °C for 5 h.… Click to show full abstract

Abstract Tb 3+ /Yb 3+ co-doped Y 2 O 3 transparent ceramics were fabricated by vacuum sintering of the pellets (prepared from nanopowders by uniaxial pressing) at 1750 °C for 5 h. Zr 4+ and La 3+ ions were incorporated in Tb 3+ /Yb 3+ co-doped Y 2 O 3 nanoparticle to reduce the formation of pores which limits the transparency of ceramic. An optical transmittance of ∼80% was achieved in ∼450 to 2000 nm range for 1 mm thick pellet which is very close to the theoretical value by taking account of Fresnel’s correction. High intensity luminescence peak at 543 nm (green) was observed in these transparent ceramics under 976 and 929 nm excitations due to Yb–Tb energy transfer upconversion.

Keywords: transparent ceramics; tb3 yb3; doped y2o3; transparent; y2o3 upconversion; yb3 doped

Journal Title: Journal of The European Ceramic Society
Year Published: 2017

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