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Porous co-continuous mullite structures obtained from sintered aluminum hydroxide and synthetic amorphous silica

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Abstract Porous materials produced from sintered Al(OH) 3 show a potentially useful α-Al 2 O 3 -based coral-like co-continuous microstructure of high porosity (above 70%) and chemical resistance. However, due… Click to show full abstract

Abstract Porous materials produced from sintered Al(OH) 3 show a potentially useful α-Al 2 O 3 -based coral-like co-continuous microstructure of high porosity (above 70%) and chemical resistance. However, due to the lack of efficient connections among the particles of the solid phase, their poor mechanical properties limit their use in biomechanical and thermo-mechanical applications, as scaffolds for bone tissue and hot air filters, respectively. In this study, authors improved these connections reinforcing the structure with a sintering aid (synthetic amorphous silica, SAS). Al(OH) 3 particles (previously sintered at 1500 °C, 5 h) were imbibed with SAS particles, compacted and sintered at 1300 °C, which generated a coral-like mullite-based porous structure. The porosity levels of the material (47%) were similar to those of the initial green state (50%) and achieved high levels of mechanical properties (flexural strength of 50.29 MPa, elastic modulus of 26.00 GPa), with small linear thermal shrinkage (lower than 6% at 1500 °C).

Keywords: porous continuous; mullite structures; synthetic amorphous; continuous mullite; amorphous silica

Journal Title: Journal of The European Ceramic Society
Year Published: 2017

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