Abstract Porous ceramics that exhibit porosity gradient are considered promising materials from the industrial point of view, especially for the production of ceramic membranes and filters. This paper describes a… Click to show full abstract
Abstract Porous ceramics that exhibit porosity gradient are considered promising materials from the industrial point of view, especially for the production of ceramic membranes and filters. This paper describes a simple and versatile approach to produce ceramics with porosity gradient. In order to perform this study, MnO 2 /SnO 2 bi-layered pellets were conformed via uniaxial pressure and sintered at 1100 °C and 1300 °C for different times. MnO 2 layer had the role of sintering aid, while the SnO 2 layer was chosen as ceramic matrix subjected to the densification. The field emission scanning electron microscope (FE-SEM) was employed to obtain information on the microstructural features of these pellets. FE-SEM micrographs revealed that the overall percentage of porosity, pore size and shape in SnO 2 layer can be controlled by sintering variables (temperature and time). The results indicated a correlation between the porosity gradient in SnO 2 with the Mn concentration gradient in this matrix.
               
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