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Fabrication and mechanical properties of carbon fibers/lithium aluminosilicate ceramic matrix composites reinforced by in-situ growth SiC nanowires

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Abstract To improve the mechanical properties of carbon fibers/lithium aluminosilicate (Cf/LAS) composites, Cf/LAS with in-situ grown SiC nanowires (SiCnw-Cf/LAS) were prepared by chemical vapor phase reaction, precursor impregnation, and hot… Click to show full abstract

Abstract To improve the mechanical properties of carbon fibers/lithium aluminosilicate (Cf/LAS) composites, Cf/LAS with in-situ grown SiC nanowires (SiCnw-Cf/LAS) were prepared by chemical vapor phase reaction, precursor impregnation, and hot press sintering, consecutively. The effect of multi-scaled reinforcements (micro-scaled Cf and nano-scaled SiCnw) on the mechanical properties was investigated. The phase composition, microstructure and fracture surface of the composites were characterized by XRD, Raman Spectrum, SEM, and TEM. The morphology of SiCnw has a close relation with the content of Si. Microstructure analysis suggests that the growth of SiC nanowires depends on the VLS mechanism. The multi-scale reinforcement formed by Cf and SiCnw can significantly improve the mechanical properties of Cf/LAS. The bending strength of SiCnw-Cf/LAS reaches to 597 MPa, achieving an increase of 19% to Cf/LAS. Moreover, the samples show a maximum fracture toughness of 11.01 MPa m1/2, achieving an increase of 46.4% to Cf/LAS. Through analysis of the fracture surface, the improved mechanical properties could be attributed to the multi-scaled reinforcements by the pull-out and debonding of Cf and SiCnw from the composites.

Keywords: properties carbon; lithium aluminosilicate; mechanical properties; fibers lithium; carbon fibers; sic nanowires

Journal Title: Journal of The European Ceramic Society
Year Published: 2019

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