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Order–disorder transition in the Dy0.2Sr0.8CoO3-δ rare-earth cobalt oxide solid solutions: Structural and thermoelectric properties

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Abstract By the example of the Dy0.2Sr0.8CoO3-δ compound undergoing an order–disorder phase transition with increasing temperature, we demonstrate a significant dependence of the kinetic properties on the morphology of the… Click to show full abstract

Abstract By the example of the Dy0.2Sr0.8CoO3-δ compound undergoing an order–disorder phase transition with increasing temperature, we demonstrate a significant dependence of the kinetic properties on the morphology of the internal spatially inhomogeneous structure, which forms in the sample depending on the rate of its transition from the high-temperature disordered cubic phase to the ground tetragonal ordered phase upon cooling. The results of transmission electron microscopy visualization of the spatially inhomogeneous state in the Dy0.2Sr0.8CoO3-δ ceramic samples are presented and compared with the X-ray diffraction data.

Keywords: 2sr0 8coo3; order disorder; transition; dy0 2sr0

Journal Title: Journal of The European Ceramic Society
Year Published: 2020

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