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3D printing of PDC-SiOC@SiC twins with high permittivity and electromagnetic interference shielding effectiveness

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Abstract Effective electromagnetic interference (EMI) shielding requires materials with high permittivity. The current study reports 3D printed polymer-derived SiOC ceramics (PDC) modified with SiC nanowires (SiCnw) exhibiting both high real… Click to show full abstract

Abstract Effective electromagnetic interference (EMI) shielding requires materials with high permittivity. The current study reports 3D printed polymer-derived SiOC ceramics (PDC) modified with SiC nanowires (SiCnw) exhibiting both high real and imaginary parts of permittivity within X-band. SEM results indicated that a large number of pores and cracks exist in the SiOC, and twinned SiCnw were uniformly grown among them along with the existence of graphite microcrystals when the sintering temperature was 1500 ℃. The real part of permittivity ranged from 16.6 to 28.9 while the imaginary part from 31.7 to 34.2 in X-band. The EMI total shielding effectiveness (SET) of the ceramics could reach 34.7 dB with absorption loss (SEA) of 29.3 dB and reflection loss (SER) of 5.4 dB. Meanwhile, the 3D printed PDC-SiOC ceramics at 900 ℃ sintering temperature possess certain mechanical properties with the magnitude of compressive strength being 12.57 MPa.

Keywords: high permittivity; sioc; pdc sioc; electromagnetic interference; shielding effectiveness; permittivity

Journal Title: Journal of The European Ceramic Society
Year Published: 2021

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