LAUSR

Abstract Ti2AlC film can be used as a protective coating for fuel cladding materials and structural materials in nuclear reactors. However, the related radiation damage and the helium (He) effects have not been well understood. In this work, the He radiation effects on Ti2AlC thin films, deposited by reactive magnetron sputtering, were studied. In addition to the detailed characterization of the radiation-induced defects and He bubbles, phase transformation was identified and investigated during film deposition, ion irradiation, and subsequent annealing. Results suggested that the hexagonal close-packed (hcp) Ti2AlC was formed from a solid-solution face-centered cubic (fcc) (Ti2Al)C phase during the film deposition process. A phase transformation from hcp-Ti2AlC to fcc-(Ti2Al)C happened during the He ion irradiation, while a reversible phase transformation from fcc-(Ti2Al)C to hcp-Ti2AlC occurred during the post annealings at temperatures above 600 °C. The reversible phase transformation indicates dynamic restoration of this material and provides insights into the design of new irradiation-damage-tolerant ceramic materials.