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Iron diffusivity into superconducting YBa2Cu3O7−δ at oxygen-assisted sintering: structural, magnetic, and transport properties

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Abstract Optimization of materials exhibiting high temperature superconductivity for producing controllable nano-devices is crucial for industrial applications. Herein we report a comprehensive study of the diffusion process between YBa2Cu3O7-δ (YBCO)… Click to show full abstract

Abstract Optimization of materials exhibiting high temperature superconductivity for producing controllable nano-devices is crucial for industrial applications. Herein we report a comprehensive study of the diffusion process between YBa2Cu3O7-δ (YBCO) and iron particles. Fe diffusion into the YBCO matrix could be fundamental for multilayer systems with YBCO/Fe-alloy interfaces. We have found that the orthorhombic YBCO structure adopts to 3 wt% Fe, while for higher Fe content, a formation of BaFeO3−δ and iron oxides was observed. Complementary measurements confirmed the strong superconductivity suppression in YBCO-Fe materials containing more than 7 wt% Fe. The YBCO with diffused Fe material retain the unit cell orthorhombicity (max. 3 wt% Fe), and their superconducting properties follow the principle of critical scaling with different exponents (γ). The critical current density (Jc), pinning fields (HP) exhibit γ = 1, the first critical field (Hc1) shows γ = 1/2, and critical temperature (Tc) demonstrates γ = 7/4.

Keywords: ybco; yba2cu3o7 oxygen; oxygen assisted; iron diffusivity; diffusivity superconducting; superconducting yba2cu3o7

Journal Title: Journal of The European Ceramic Society
Year Published: 2021

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