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Effects of B2O3 substitution for Al2O3 on the crystallization and properties of translucent mica glass-ceramics

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Abstract The effects of substituting Al2O3 with B2O3 on the structure, crystallization, mechanical properties, thermal properties and optical properties of translucent mica glass-ceramics were thoroughly investigated. The results demonstrated that… Click to show full abstract

Abstract The effects of substituting Al2O3 with B2O3 on the structure, crystallization, mechanical properties, thermal properties and optical properties of translucent mica glass-ceramics were thoroughly investigated. The results demonstrated that the addition of 0.5 wt% B2O3 was optimum for glass precipitation, which increases the crystallinity of glass-ceramics and provides good translucency. When the content of B2O3 was greater than 0.5 wt%, both crystallinity and translucency decreased noticeably. The replacement of B2O3 for Al2O3 had no influence on the type of crystal phase and the precipitation of tetrasilicic fluoromica with non-stoichiometric ratio, while it did have an effect on the crystallinity and structure. The crystal sizes of glass-ceramics were in the nanoscale range and the transmittance test results indicated that they exhibit excellent translucency.

Keywords: glass; mica glass; glass ceramics; properties translucent; translucent mica; b2o3

Journal Title: Journal of the European Ceramic Society
Year Published: 2021

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