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Abstract A copper-mediated oxidative pentafluoroethylthiolation of aryl boronic acids with TMSC 2 F 5 and S 8 was developed. This reaction provides a new access to various aryl pentafluoroethyl thioethers.… Click to show full abstract
Abstract A copper-mediated oxidative pentafluoroethylthiolation of aryl boronic acids with TMSC 2 F 5 and S 8 was developed. This reaction provides a new access to various aryl pentafluoroethyl thioethers. The use of 2-fluoropyridine as the ligand and the ability to carry out the reaction at 70 °C are key features of this oxidative coupling reaction.
Keywords:
boronic acids;
mediated oxidative;
copper mediated;
pentafluoroethylthiolation aryl;
aryl boronic;
oxidative pentafluoroethylthiolation
Journal Title: Journal of Fluorine Chemistry
Year Published: 2017
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Journal Title: Journal of Fluorine Chemistry
Year Published: 2017
Link to full text (if available)
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recommendations!