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Abstract Herein we report the synthesis and X-ray crystallographic study of a per(meta-t-butyl) substituted trityl fluoride in order to explore possible intermolecular F F interactions, as inspired by the recent… Click to show full abstract
Abstract Herein we report the synthesis and X-ray crystallographic study of a per(meta-t-butyl) substituted trityl fluoride in order to explore possible intermolecular F F interactions, as inspired by the recent work of Schreiner et al. on close H contacts. Instead of proximate F atoms, we uncovered an unusual ordering effect caused by an interaction between the polar fluorine and nearby C H bonds, a result that may carry some interest in regards to fluorinated compounds’ interactions with enzymes.
Keywords:
synthesis ray;
substituted trityl;
trityl fluoride;
ray crystallography
Journal Title: Journal of Fluorine Chemistry
Year Published: 2019
Link to full text (if available)
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Journal Title: Journal of Fluorine Chemistry
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!