Photo from archive.org
Abstract New electrophilic fluorination reagent HF·THF/PhIO was introduced and tested on three general classes of compounds. Compared with the literature data reported for basic reagents, such as HF/TEA/PhIO and HF/Py/PhIO,… Click to show full abstract
Abstract New electrophilic fluorination reagent HF·THF/PhIO was introduced and tested on three general classes of compounds. Compared with the literature data reported for basic reagents, such as HF/TEA/PhIO and HF/Py/PhIO, the new reagent showed superior performance in fluorination of aromatic alkenes, subpar reactivity with ketones and malonates, while in the reactions with 1,3-unsaturated carbonyl compounds the results were much the same as the literature data.
Keywords:
reagent;
using phio;
fluorination;
phio thf;
fluorination using;
electrophilic fluorination
Journal Title: Journal of Fluorine Chemistry
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Journal of Fluorine Chemistry
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!