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High-color rendering index white organic light-emitting diodes based on exciplex forming blue emitters

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Abstract A novel emitting layer structure of white organic light-emitting diodes (WOLED) was developed using exciplex-forming two blue emitters, 2,3,4,5,6-penta(9H-carbazol-9-yl)benzonitrile (5CzCN) and tris(2-(1-(2,4-diisopropyldibenzo[b,d]furan-3-yl)-1H-imidazol-2-yl)phenyl)iridium (Ir(dbi) 3 ). The 5CzCN blue delayed… Click to show full abstract

Abstract A novel emitting layer structure of white organic light-emitting diodes (WOLED) was developed using exciplex-forming two blue emitters, 2,3,4,5,6-penta(9H-carbazol-9-yl)benzonitrile (5CzCN) and tris(2-(1-(2,4-diisopropyldibenzo[b,d]furan-3-yl)-1H-imidazol-2-yl)phenyl)iridium (Ir(dbi) 3 ). The 5CzCN blue delayed fluorescence material and Ir(dbi) 3 phosphorescent emitter partially formed a red exciplex in the mixed film. Combination of blue emission from the blue emitters and red emission from the exciplex provided white emission in the blue emitting 5CzCN and Ir(dbi) 3 co-doped device. The WOLED fabricated using the blue emitting 5CzCN and Ir(dbi) 3 emitters achieved high color rendering index of 90.8 at 100 cd/m 2 .

Keywords: exciplex forming; blue emitters; organic light; emitting diodes; light emitting; white organic

Journal Title: Journal of Industrial and Engineering Chemistry
Year Published: 2017

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