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Hydrogenation of methyl methacrylate under mild conditions using biosynthesis Ru catalyst

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Abstract Hydrogenation of methyl methacrylate (MMA) was investigated over Ru-based catalyst supported on active carbons (AC), which was prepared by bio-reduction method, using C. Platycladi (CP) leaf extract as reductant.… Click to show full abstract

Abstract Hydrogenation of methyl methacrylate (MMA) was investigated over Ru-based catalyst supported on active carbons (AC), which was prepared by bio-reduction method, using C. Platycladi (CP) leaf extract as reductant. By varying reaction temperature, hydrogen pressure and reaction time, hydrogenation of MMA over the biosynthesis Ru-based catalyst was carried out, and resulted the optimum conditions, 30 °C (room temperature), 2.0 MPa, and 50 min. The as-prepared Ru/AC catalyst showed high catalytic activity towards the hydrogenation of MMA, affording 100% of MMA conversion even under mild conditions without solvent and methyl isobutyrate was the only product.

Keywords: mild conditions; hydrogenation; methyl methacrylate; catalyst; hydrogenation methyl

Journal Title: Journal of Industrial and Engineering Chemistry
Year Published: 2017

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