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Low temperature oxidation characteristics analysis of ultra-heavy oil by thermal methods

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Abstract To study the oxidation behavior of heavy oils, low temperature oxidation experiments under differential temperature and pressure conditions were carried out for both heavy oils (ordinary heavy and ultra-heavy… Click to show full abstract

Abstract To study the oxidation behavior of heavy oils, low temperature oxidation experiments under differential temperature and pressure conditions were carried out for both heavy oils (ordinary heavy and ultra-heavy oils) with thermogravimetry (TG–DTG)/differential scanning calorimeter (DSC) analyses. And the results indicated that the differences of physical properties and oxidation reactions for the heavy oils ascribe to the SARA compositions, H/C ratio and specific oxidation path. Owing to the asphaltenes content, the ultra-heavy oil after the oxidation has more obvious coke deposition with lower activation energy demand to make it possible for the in-situ combustion without combustion adjuvants.

Keywords: heavy oils; temperature oxidation; low temperature; oxidation; ultra heavy

Journal Title: Journal of Industrial and Engineering Chemistry
Year Published: 2017

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