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Enhancing performance of La0.8Sr0.2MnO3−δ-infiltrated Er0.4Bi1.6O3 cathodes via controlling wettability and catalyst loading of the precursor solution for IT-SOFCs

Abstract La0.8Sr0.2MnO3−δ (LSM) nanocatalyst-decorated Er0.4Bi1.6O3 (ESB) cathodes for IT-SOFCs were developed via an infiltration technique. Using different amounts of Triton-X 100 significantly changed the wettability of the LSM precursor solution,… Click to show full abstract

Abstract La0.8Sr0.2MnO3−δ (LSM) nanocatalyst-decorated Er0.4Bi1.6O3 (ESB) cathodes for IT-SOFCs were developed via an infiltration technique. Using different amounts of Triton-X 100 significantly changed the wettability of the LSM precursor solution, thus affecting final characteristics of the LSM nanoparticles. The best electrochemical performance was obtained at a 1:1 ratio of LSM and Triton-X 100. Furthermore, tuning the LSM concentration tailored the size and porosity of LSM nanocatalysts. The ASR of the optimized LSM-infiltrated ESB cathode on GDC electrolyte was as low as 0.16 Ω-cm2 at 650 °C, the lowest ASR among reported LSM-stabilized bismuth oxide cathodes fabricated by the infiltration method.

Keywords: 4bi1 6o3; er0 4bi1; 8sr0 2mno3; la0 8sr0; wettability; precursor solution

Journal Title: Journal of Industrial and Engineering Chemistry
Year Published: 2017

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