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Fluorescence switching of BSA–[Fe(III)–salen]Cl and implementation of its multiple logic gates

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Abstract In this study, [Fe(III)–salen]Cl (complex 1 ) was synthesized and its interaction with bovine serum albumin (BSA) was investigated by fluorescence spectroscopy. The estimated distance between BSA and 1… Click to show full abstract

Abstract In this study, [Fe(III)–salen]Cl (complex 1 ) was synthesized and its interaction with bovine serum albumin (BSA) was investigated by fluorescence spectroscopy. The estimated distance between BSA and 1 indicated that energy transfer from the excited state of BSA to 1 was achieved with high efficiency. BSA sensors based on fluorescent off–on ( 1 - Na 2 H 2 EDTA) and on–off (OH − –H + ) were examined and the results confirmed that BSA could operate as molecular logic gate upon interaction with 1 , Na 2 H 2 EDTA, and OH − as chemical inputs. Multiple logic gates including NOR, NOT, and IMP were constructed through consecutive association of 1 with BSA.

Keywords: iii salen; bsa; switching bsa; fluorescence switching; multiple logic; logic gates

Journal Title: Journal of Luminescence
Year Published: 2017

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