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Photoluminescence as a probe of molecular organization in PDI8-CN2 ultra-thin films

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Abstract Photoexcited ultra-thin films of the organic semiconductor N,N'-bis( n -octyl)-dicyanoperylene-3,4:9,10-bis dicarboximide (DPI8-CN2), grown on thermal Si/SiO 2 , exhibit an intense room temperature emission, strongly dependent on molecular coverage,… Click to show full abstract

Abstract Photoexcited ultra-thin films of the organic semiconductor N,N'-bis( n -octyl)-dicyanoperylene-3,4:9,10-bis dicarboximide (DPI8-CN2), grown on thermal Si/SiO 2 , exhibit an intense room temperature emission, strongly dependent on molecular coverage, even for sub-monolayer thicknesses. The luminescence spectra are characterized by a highly structured, isolated molecule emission in the sub-monolayer regime (coverage

Keywords: cn2; thin films; ultra thin; probe molecular; molecular organization; photoluminescence probe

Journal Title: Journal of Luminescence
Year Published: 2017

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