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Low Temperature Synthesis of CsPbI 3 Sub-micrometer Wires with Tailored Emission Band for Flexible X-ray Phosphors Applications

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Abstract CsPbI 3 sub-micrometer wires were synthesized by one-pot solution method at near room temperature. The wires are single crystalline with [100] orientation. An strong emission band centered at 470 nm… Click to show full abstract

Abstract CsPbI 3 sub-micrometer wires were synthesized by one-pot solution method at near room temperature. The wires are single crystalline with [100] orientation. An strong emission band centered at 470 nm was observed under ultraviolet excitation, and the emission intensity and bandwidth are dependent on the molar ratio of CsI/PbI 2 in the wires. A bright green emission with a lifetime of several tens ns was observed when excited with a soft X-ray, and the spectral response range can be modulated by the molar ratio of CsI/PbI 2 in the wires. The growth mechanism of the wires was discussed, and the influences of the cycling strain and X-ray irrigation time on the X-ray excited optical luminescence of the CsI/PbI 2 wires/PET film were analyzed and discussed.

Keywords: ray; emission band; sub micrometer; micrometer wires; cspbi sub; emission

Journal Title: Journal of Luminescence
Year Published: 2017

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