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Ellagic acid-functionalized fluorescent carbon dots for ultrasensitive and selective detection of mercuric ions via quenching

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Abstract The authors report on a strategy for the fabrication of water soluble carbon quantum dots (CDs) functionalized with ellagic acid. They also demonstrate highly selective detection of Hg 2+… Click to show full abstract

Abstract The authors report on a strategy for the fabrication of water soluble carbon quantum dots (CDs) functionalized with ellagic acid. They also demonstrate highly selective detection of Hg 2+ ions in aqueous media via fluorescence quenching. The CDs were prepared via a one-step technique using tannic acid as the carbon source and directly surface functionalized during nanoparticle synthesis. Following photoexcitation at 210 nm they exhibit excitation-independent emission that peaks at 340 nm. The CDs display strong affinity for Hg 2+ and binding result in quenching of fluorescence. This effect can be used to quantify Hg 2+ in concentration down to 10 pM and with detection limit as low as 0.24 pM. The ultrasensitive detection of Hg 2+ ions is demonstrated by analyzing Hg 2+ -spiked water and tap-water samples.

Keywords: detection; acid functionalized; carbon; functionalized fluorescent; ellagic acid; selective detection

Journal Title: Journal of Luminescence
Year Published: 2017

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